| Brotzel, Frank (2008): Nucleophilicities of Amines, Amino Acids and Pyridines. Dissertation, LMU München: Faculty of Chemistry and Pharmacy |
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Brotzel_Frank.pdf 3MB |
DOI: 10.5282/edoc.9538
Abstract
In line with earlier work of the Mayr group, diarylcarbenium ions (benzhydryl cations) Ar2CH+ have been employed as reference electrophiles for the construction of nucleophilicity scales for amines, amino acids, some di- and tripeptides, and pyridines using the relationship eq. (0.1). log k20° C = s(N + E) (0.1) k = second-order rate constant in M-1 s-1 s = nucleophile specific slope parameter N = nucleophilicity parameter E = electrophilicity parameter
| Item Type: | Theses (Dissertation, LMU Munich) |
|---|---|
| Keywords: | Kinetics, Nucleophilicity, Amine, Amino Acid, Pyridine |
| Subjects: | 500 Natural sciences and mathematics 500 Natural sciences and mathematics > 540 Chemistry and allied sciences |
| Faculties: | Faculty of Chemistry and Pharmacy |
| Language: | English |
| Date of oral examination: | 10. July 2008 |
| 1. Referee: | Mayr, Herbert |
| MD5 Checksum of the PDF-file: | 966bf74aca33f7bc5e56c238d990af5b |
| Signature of the printed copy: | 0001/UMC 17542 |
| ID Code: | 9538 |
| Deposited On: | 28. Jan 2009 13:28 |
| Last Modified: | 24. Oct 2020 06:38 |
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