| Gavryushin, Andrey (2007): Chiral Diphosphine Ligands and New Reactions of Organozinc Compounds. Dissertation, LMU München: Faculty of Chemistry and Pharmacy |
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Gavryushin_Andrey.pdf 1MB |
DOI: 10.5282/edoc.6597
Abstract
Using the [2,3]-sigmatropic rearrangement of chiral allylic diarylphosphinites, a number of new enantiopure 1,3-diphoshine ligands were prepared. Enzymatic kinetic rezolution of allylic alcohols was used for the preparation of enantiopure starting materials. Several new reactions of organozinc compounds, i. e. new thiolation method, Ni-catalyzed cross-coupling reactions and a method of preparation of alkylzinc bromides from the corresponding alkylbromides were developed.
| Item Type: | Theses (Dissertation, LMU Munich) |
|---|---|
| Keywords: | diphosphine ligands, organozinc compounds |
| Subjects: | 500 Natural sciences and mathematics 500 Natural sciences and mathematics > 540 Chemistry and allied sciences |
| Faculties: | Faculty of Chemistry and Pharmacy |
| Language: | English |
| Date of oral examination: | 9. February 2007 |
| 1. Referee: | Knochel, Paul |
| MD5 Checksum of the PDF-file: | 9f1486fdf2dbf14e2c22709d667d8d49 |
| Signature of the printed copy: | 0001/UMC 16037 |
| ID Code: | 6597 |
| Deposited On: | 15. Mar 2007 |
| Last Modified: | 24. Oct 2020 08:41 |
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