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Preparation and Reactions of Polymagnesiated Aromatics and Heteroaromatics, Functionalized Cyclopropane Carbenoids and Soluble Lanthanide Reagents
Preparation and Reactions of Polymagnesiated Aromatics and Heteroaromatics, Functionalized Cyclopropane Carbenoids and Soluble Lanthanide Reagents
A synthetic access to polymagnesiated aromatics and heteroaromatics via multiple magnesiations was developed, their reactivity towards different electrophiles was explored. A diatereoselective synthesis of functionalized cyclopropane carbenoids was developed. Soluble Lanthanide soloutions were prepared and used in the addition reactions of Grignard reagents to carbonyl compounds.
magnesium, halogen/magnesium exchange, Grignard reaction, carbenoids, lanthanides
Kopp, Felix
2007
English
Universitätsbibliothek der Ludwig-Maximilians-Universität München
Kopp, Felix (2007): Preparation and Reactions of Polymagnesiated Aromatics and Heteroaromatics, Functionalized Cyclopropane Carbenoids and Soluble Lanthanide Reagents. Dissertation, LMU München: Faculty of Chemistry and Pharmacy
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Abstract

A synthetic access to polymagnesiated aromatics and heteroaromatics via multiple magnesiations was developed, their reactivity towards different electrophiles was explored. A diatereoselective synthesis of functionalized cyclopropane carbenoids was developed. Soluble Lanthanide soloutions were prepared and used in the addition reactions of Grignard reagents to carbonyl compounds.