Preparation and Reactions of Polymagnesiated Aromatics and Heteroaromatics, Functionalized Cyclopropane Carbenoids and Soluble Lanthanide Reagents

Kopp, Felix (2007): Preparation and Reactions of Polymagnesiated Aromatics and Heteroaromatics, Functionalized Cyclopropane Carbenoids and Soluble Lanthanide Reagents. Dissertation, LMU München: Fakultät für Chemie und Pharmazie

Abstract

A synthetic access to polymagnesiated aromatics and heteroaromatics via multiple magnesiations was developed, their reactivity towards different electrophiles was explored. A diatereoselective synthesis of functionalized cyclopropane carbenoids was developed. Soluble Lanthanide soloutions were prepared and used in the addition reactions of Grignard reagents to carbonyl compounds.

• Dokumententyp: Dissertationen (Dissertation, LMU München)
• Keywords: magnesium, halogen/magnesium exchange, Grignard reaction, carbenoids, lanthanides
• Themengebiete: 500 Naturwissenschaften und Mathematik ; 500 Naturwissenschaften und Mathematik > 540 Chemie
• Fakultäten: Fakultät für Chemie und Pharmazie
• Sprache der Hochschulschrift: Englisch
• Datum der mündlichen Prüfung: 7. Februar 2007
• 1. Bericht­erstatter:in: Knochel, Paul