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Copper(I)-Mediated Regio- and Stereoselective Allylic Substitutions and Their Applications to Natural Product Syntheses
Copper(I)-Mediated Regio- and Stereoselective Allylic Substitutions and Their Applications to Natural Product Syntheses
This work focused on the copper(I)-mediated stereoselective anti-allylic substitution reactions using organozinc reagents and chiral cyclic phosphates or pentafluorobenzoates. The applications of this method to the preparation of natural products were also reported.
allylic substitutions, organocopper, organozinc
Soorukram, Darunee
2006
English
Universitätsbibliothek der Ludwig-Maximilians-Universität München
Soorukram, Darunee (2006): Copper(I)-Mediated Regio- and Stereoselective Allylic Substitutions and Their Applications to Natural Product Syntheses. Dissertation, LMU München: Faculty of Chemistry and Pharmacy
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Abstract

This work focused on the copper(I)-mediated stereoselective anti-allylic substitution reactions using organozinc reagents and chiral cyclic phosphates or pentafluorobenzoates. The applications of this method to the preparation of natural products were also reported.