| Nigst, Tobias Alexander (2012): Reactivity parameters for nitrogen nucleophiles: from the alpha-effect to applications as organocatalysts and photo-leaving groups. Dissertation, LMU München: Faculty of Chemistry and Pharmacy |
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Nigst_Tobias_A.pdf 5MB |
DOI: 10.5282/edoc.14998
Abstract
The nucleophilic reactivities of amines, hydrazines, and pyridines were quantified using benzhydrylium ions and quinone methides as reference electrophiles. The scope and limitations of the linear free energy relationship log k2 = sN(N+E) for predicting rates of the reactions of carbocations and acylation agents was studied.
| Item Type: | Theses (Dissertation, LMU Munich) |
|---|---|
| Keywords: | Nucleophilicity, Acylation Reactions, Kinetics, Linear Free Energy Relationship, Carbocations |
| Subjects: | 500 Natural sciences and mathematics 500 Natural sciences and mathematics > 540 Chemistry and allied sciences |
| Faculties: | Faculty of Chemistry and Pharmacy |
| Language: | English |
| Date of oral examination: | 11. October 2012 |
| 1. Referee: | Mayr, Herbert |
| MD5 Checksum of the PDF-file: | 934b3e45af816a6a134dd8da4e74d11c |
| Signature of the printed copy: | 0001/UMC 20731 |
| ID Code: | 14998 |
| Deposited On: | 08. Nov 2012 10:20 |
| Last Modified: | 24. Oct 2020 01:46 |
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