| Brotzel, Frank (2008): Nucleophilicities of Amines, Amino Acids and Pyridines. Dissertation, LMU München: Faculty of Chemistry and Pharmacy |
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PDF
Brotzel_Frank.pdf 2939Kb |
Abstract
In line with earlier work of the Mayr group, diarylcarbenium ions (benzhydryl cations) Ar2CH+ have been employed as reference electrophiles for the construction of nucleophilicity scales for amines, amino acids, some di- and tripeptides, and pyridines using the relationship eq. (0.1). log k20° C = s(N + E) (0.1) k = second-order rate constant in M-1 s-1 s = nucleophile specific slope parameter N = nucleophilicity parameter E = electrophilicity parameter
| Item Type: | Thesis (Dissertation, LMU Munich) | |
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| Keywords: | Kinetics, Nucleophilicity, Amine, Amino Acid, Pyridine | |
| Subjects: | 600 Natural sciences and mathematics 600 Natural sciences and mathematics > 540 Chemistry and allied sciences | |
| Faculties: | Faculty of Chemistry and Pharmacy | |
| Language: | English | |
| Date Accepted: | 10. July 2008 | |
| 1. Referee: | Mayr, Herbert | |
| Persistent Identifier (URN): | urn:nbn:de:bvb:19-95388 | |
| MD5 Checksum of the PDF-file: | 966bf74aca33f7bc5e56c238d990af5b | |
| Signature of the printed copy: | 0001/UMC 17542 | |
| ID Code: | 9538 | |
| Deposited On: | 28. Jan 2009 13:28 | (UTC) |
| Last Modified: | 16. Oct 2012 08:24 | (UTC) |
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