Logo Logo
Hilfe
Kontakt
Switch language to English
Nucleophilicities of Amines, Amino Acids and Pyridines
Nucleophilicities of Amines, Amino Acids and Pyridines
In line with earlier work of the Mayr group, diarylcarbenium ions (benzhydryl cations) Ar2CH+ have been employed as reference electrophiles for the construction of nucleophilicity scales for amines, amino acids, some di- and tripeptides, and pyridines using the relationship eq. (0.1). log k20° C = s(N + E) (0.1) k = second-order rate constant in M-1 s-1 s = nucleophile specific slope parameter N = nucleophilicity parameter E = electrophilicity parameter
Kinetics, Nucleophilicity, Amine, Amino Acid, Pyridine
Brotzel, Frank
2008
Englisch
Universitätsbibliothek der Ludwig-Maximilians-Universität München
Brotzel, Frank (2008): Nucleophilicities of Amines, Amino Acids and Pyridines. Dissertation, LMU München: Fakultät für Chemie und Pharmazie
[thumbnail of Brotzel_Frank.pdf]
Vorschau
PDF
Brotzel_Frank.pdf

3MB

Abstract

In line with earlier work of the Mayr group, diarylcarbenium ions (benzhydryl cations) Ar2CH+ have been employed as reference electrophiles for the construction of nucleophilicity scales for amines, amino acids, some di- and tripeptides, and pyridines using the relationship eq. (0.1). log k20° C = s(N + E) (0.1) k = second-order rate constant in M-1 s-1 s = nucleophile specific slope parameter N = nucleophilicity parameter E = electrophilicity parameter