| Kopp, Felix (2007): Preparation and Reactions of Polymagnesiated Aromatics and Heteroaromatics, Functionalized Cyclopropane Carbenoids and Soluble Lanthanide Reagents. Dissertation, LMU München: Faculty of Chemistry and Pharmacy |
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PDF
Kopp_Felix.pdf 1649Kb |
Abstract
A synthetic access to polymagnesiated aromatics and heteroaromatics via multiple magnesiations was developed, their reactivity towards different electrophiles was explored. A diatereoselective synthesis of functionalized cyclopropane carbenoids was developed. Soluble Lanthanide soloutions were prepared and used in the addition reactions of Grignard reagents to carbonyl compounds.
| Item Type: | Thesis (Dissertation, LMU Munich) | |
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| Keywords: | magnesium, halogen/magnesium exchange, Grignard reaction, carbenoids, lanthanides | |
| Subjects: | 600 Natural sciences and mathematics 600 Natural sciences and mathematics > 540 Chemistry and allied sciences | |
| Faculties: | Faculty of Chemistry and Pharmacy | |
| Language: | English | |
| Date Accepted: | 7. February 2007 | |
| 1. Referee: | Knochel, Paul | |
| Persistent Identifier (URN): | urn:nbn:de:bvb:19-65845 | |
| MD5 Checksum of the PDF-file: | d2465cdc74429092e02b02ccff0c6066 | |
| Signature of the printed copy: | 0001/UMC 16036 | |
| ID Code: | 6584 | |
| Deposited On: | 15. Mar 2007 | (UTC) |
| Last Modified: | 16. Oct 2012 08:05 | (UTC) |
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