| Perrone, Sylvie (2006): Copper(I)-mediated anti-SN2’ Allylic Substitution Reactions with Diorganozinc Reagents. Dissertation, LMU München: Faculty of Chemistry and Pharmacy |
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PDF
Perrone_Sylvie.pdf 1221Kb |
Abstract
This work has been focused on the use of copper(I)-mediated anti-SN2’ allylic substitution reactions with non directing leaving groups. This proved to be a general and highly reliable method for the preparation of new chiral stereogenic centers in high enantioselectivity. Moreover a particular effort was made to apply this method to more complex systems, and compounds like alcohols, amines, alkenylsilanes or unsaturated nitriles could be successfully prepared in their enantiomerically enriched form.
| Item Type: | Thesis (Dissertation, LMU Munich) | |
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| Keywords: | allylic substitution, copper, zinc, quaternary center, asymmetric synthesis | |
| Subjects: | 600 Natural sciences and mathematics > 540 Chemistry and allied sciences 600 Natural sciences and mathematics | |
| Faculties: | Faculty of Chemistry and Pharmacy | |
| Language: | English | |
| Date Accepted: | 11. December 2006 | |
| 1. Referee: | Knochel, Paul | |
| Persistent Identifier (URN): | urn:nbn:de:bvb:19-62183 | |
| MD5 Checksum of the PDF-file: | d189a26c399c85322c3b86d6cd8711d3 | |
| Signature of the printed copy: | 0001/UMC 15869 | |
| ID Code: | 6218 | |
| Deposited On: | 20. Dec 2006 | (UTC) |
| Last Modified: | 16. Oct 2012 08:03 | (UTC) |
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